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Ytterbium


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Atomic symbol: Yb
Atomic number: 70
Atomic weight: 173.04
Atomic volume: 24.79 cm3/mol
Density: 6.98 g/cm3
Period Number: 6
Group number: none
Group name: Rare Earth, Lanthanides
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1097.2 K
Boiling point: 1700 K
Heat of fusion: 7.660 kJ/mol
Heat of vaporization: 128.90 kJ/mol


Energies


Ionization Energy: 6.254 eV
1st ionization energy: 603.4 kJ/mole
2nd ionization energy: 1176 kJ/mole
3rd ionization energy: 2415 kJ/mole
Electronegativity: 1.21
Electron affinity: 50 kJ/mole
Specific heat: 0.15 J/gK
Heat atomization: 152 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,32,8,2
Electron Shell Configuration: [Xe] 4f14 6s2
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: fcc: face-centered cubic
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: soft
Uses: alloys


Reactions


Reaction with air: vigorous, =>Yb2O3
Reaction with 6M HCl: mild, =>H2, YbCl3
Reaction with 15M HNO3: mild, =>Yb(NO3)3
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 7
Oxide(s): Yb2O3
Hydride(s): YbH2 Yb2H5
Chloride(s): YbCl2 YbCl3


Radius


Atomic Radius: 193 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): 116 pm
Ionic radius (3+ ion): 100.8 pm


Conductivity


Thermal conductivity: 34.9 J/m-sec-deg
Electrical conductivity: 35.7 1/mohm-cm
Polarizability: 21 A^3


Abundance


Source: Monazite(phosphate),bastnaesite
Relative abundance solar system: -0.606 log
Abundance earth's crust: 0.5 log
Estimated crustal abundance: 3.2 milligrams per kilogram
Estimated oceanic abundance: 8.2×10-7 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Ytterby, village in Sweden) Marignac in 1878 discovered a new component, which he called ytterbia, in the earth then known as erbia. In 1907, Urbain separated ytterbia into two components, which he called neoytterbia and lutecia. The elements in these earths are now known as ytterbium and lutetium, respectively. These elements are identical with aldebaranium and cassiopeium, discovered independently and at about the same time by von Welsbach.


Sources


Ytterbium occurs along with other rare earths in a number of rare minerals. It is commercially recovered principally from monazite sand, which contains about 0.03%. Ion-exchange and solvent extraction techniques developed in recent years have greatly simplified the separation of the rare earths from one another.


Properties


Ytterbium has a bright silvery luster, is soft, malleable, and quite ductile. Even though the element is fairly stable, it should be kept in closed containers to protect it from air and moisture. Ytterbium is readily attacked and dissolved by dilute and concentrated mineral acids and reacts slowly with water. Ytterbium has three allotropic forms with transformation points at -130C and 7950C: The beta form is a room-temperature, face-centered, cubic modification, while the high-temperature gamma form is a body-centered cubic form. Another body-centered cubic phase has recently been found to be stable at high pressures at room temperatures. The beta form ordinarily has metallic-type conductivity, but becomes a semiconductor when the pressure is increased about 16,000 atm. The electrical resistance increases tenfold as the pressure is increased to 39,000 atm and drops to about 10% of its standard temperature-pressure resistivity at a pressure of 40,000 atm. Natural ytterbium is a mixture of seven stable isotopes. Seven other unstable isotopes are known.


Uses


Ytterbium metal has possible use in improving the grain refinement, strength, and other mechanical properties of stainless steel. One isotope is reported to have been used as a radiation source substitute for a portable X-ray machine where electricity is unavailable. Few other uses have been found.

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