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Niobium


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Atomic symbol: Nb
Atomic number: 41
Atomic weight: 92.9064
Atomic volume: 10.87 cm3/mol
Density: 8.57 g/cm3
Period Number: 5
Group number: 5
Group name: Trans. Met.
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 2741.2 K
Boiling point: 5031 K
Heat of fusion: 26.40 kJ/mol
Heat of vaporization: 682.0 kJ/mol


Energies


Ionization Energy: 6.759 eV
1st ionization energy: 663.8 kJ/mole
2nd ionization energy: 1381.7 kJ/mole
3rd ionization energy: 2416 kJ/mole
Electronegativity: 1.6
Electron affinity: 86.2 kJ/mole
Specific heat: 0.26 J/gK
Heat atomization: 726 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,12,1
Electron Shell Configuration: [Kr] 4d4 5s1
Minimum oxidation number: -1
Maximum oxidation number: 5
Minimum common oxidation number: 0
Maximum common oxidation no: 5


Appearance & Characteristics


Structure:: bcc: body-centered cubic
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: soft
Uses: stainless steels, magnets


Reactions


Reaction with air: none, w/ht =>Nb2O3
Reaction with 6M HCl: none
Reaction with 15M HNO3: none
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 1
Oxide(s): NbO NbO2 Nb2O5
Hydride(s): NbH NbH2
Chloride(s): NbCl3 NbCl4 NbCl5


Radius


Atomic Radius: 146 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 86 pm


Conductivity


Thermal conductivity: 53.7 J/m-sec-deg
Electrical conductivity: 80 1/mohm-cm
Polarizability: 15.7 A^3


Abundance


Source: columbite (oxide)
Relative abundance solar system: -0.156 log
Abundance earth's crust: 1.3 log
Estimated crustal abundance: 2.0×101 milligrams per kilogram
Estimated oceanic abundance: 1×10-5 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Named after Niobe, the daughter of Tantalus) Discovered in 1801 by Hatchett in an ore sent to England. The metal was first prepared in 1864 by Blomstrand, who reduced the chloride by heating it in a hydrogen atmosphere. The name niobium was adopted by the International Union of Pure and Applied Chemicstry (IUPAC) in 1950 after 100 years of controversy. Many leading chemical societies and government organizations refer to it by this name. Most metallurgists, leading metal societies, and all but one of the leading U.S. commercial producers, however, still refer to the metal as "columbium."


Sources


The element is found in niobite (or columbite), niobite-tantalite, parochlore, and euxenite. Large deposits of niobium have been found associated with carbonatites (carbon-silicate rocks), as a constituent of parochlore. Extensive ore reserves are found in Canada, Brazil, Nigeria, Zaire, and in Russia.


Properties


Niobium is a shiny, white, soft, and ductile metal, and takes on a bluish cast when exposed to air at room temperatures for a long time. The metal starts to oxidize in air at 2000C, and when processed at even moderate temperatures must be placed in a protective atmosphere.


Uses


Niobium is used in arc-welding rods for stabilized grades of stainless steel. Thousands of pounds of niobium have been used in advanced air frame systems such as were used in the Gemini space program. The element has superconductive properties; superconductive magnets have been made with Nb-Zr wire, which retains its superconductivity in strong magnetic fields. This type of application offers hope of direct large-scale generation of electric power. Niobium is also commonly used for jewelry.


Isotopes


Eighteen isotopes of niobium are known. The metal can be isolated from tantalum, and prepared in several ways.

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