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Iridium


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Atomic symbol: Ir
Atomic number: 77
Atomic weight: 192.22
Atomic volume: 8.54 cm3/mol
Density: 22.42 g/cm3
Period Number: 6
Group number: 9
Group name: Trans. Met.
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 2683.2 K
Boiling point: 4823 K
Heat of fusion: 26.10 kJ/mol
Heat of vaporization: 604.0 kJ/mol


Energies


Ionization Energy: 9.1 eV
1st ionization energy: 880 kJ/mole
2nd ionization energy: kJ/mole
3rd ionization energy: kJ/mole
Electronegativity: 2.2
Electron affinity: 151 kJ/mole
Specific heat: 0.130 J/gK
Heat atomization: 665 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,32,15,2
Electron Shell Configuration: [Xe] 4f14 5d7 6s2
Minimum oxidation number: -1
Maximum oxidation number: 6
Minimum common oxidation number: 0
Maximum common oxidation no: 4


Appearance & Characteristics


Structure:: fcc: face-centered cubic
Color: white
Hardness: 6.25 mohs
Toxicity: ?
Characteristics: hard, densest el, inert
Uses: Pt/Ir sparkplugs


Reactions


Reaction with air: none
Reaction with 6M HCl: none
Reaction with 15M HNO3: none
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 2
Oxide(s): IrO2
Hydride(s): none
Chloride(s): IrCl3


Radius


Atomic Radius: 136 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 82 pm


Conductivity


Thermal conductivity: 147 J/m-sec-deg
Electrical conductivity: 188.679 1/mohm-cm
Polarizability: 7.6 A^3


Abundance


Source: nickel ores (sulfides)
Relative abundance solar system: -0.180 log
Abundance earth's crust: -3 log
Estimated crustal abundance: 1×10-3 milligrams per kilogram
Estimated oceanic abundance: No Data Available
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(L. iris: rainbow) Tennant discovered iridium in 1803 in the residue left when crude platinum is dissolved by aqua regia. The name iridium is appropriate because its salts are highly colored.


Sources


Iridium occurs uncombined in nature with platinum and other metals of this family in alluvial deposits. It is recovered as a by-product from the nickel mining industry.


Properties


Iridium, a metal of the platinum family, is white (similar to platinum) but with a slight yellowish cast. Because iridium is very hard and brittle, it is hard to machine, form, or work.

It is the most corrosion-resistant metal known, and was used in making the standard meter bar of Paris, which is a 90 percent platinum and 10 percent iridium alloy. This meter bar was replaced in 1960 as a fundamental unit of length (see Krypton).

Iridium is not attacked by any of the acids nor by aqua regia, but is attacked by molten salts, such as NaCl and NaCN. The specific gravity of iridium is to osmium's specific gravity. Calculations of the densities of iridium and osmium from the space lattices give values of 22.65 and 22.61 g/cm^3, respectively. These values may be more reliable than actual physical measurements for determining which element is heavier.


Uses


Although its principal use is as a hardening agent for platinum, iridium is also used to make crucibles and devices requiring high temperatures. It is also used for electrical contacts.

The element forms an alloy with osmium which is used for tipping pens and compass bearings.

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