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Europium


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Atomic symbol: Eu
Atomic number: 63
Atomic weight: 151.96
Atomic volume: 28.9 cm3/mol
Density: 5.259 g/cm3
Period Number: 6
Group number: none
Group name: Rare Earth
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 1095.2 K
Boiling point: 1712 K
Heat of fusion: 9.210 kJ/mol
Heat of vaporization: 143.50 kJ/mol


Energies


Ionization Energy: 5.670 eV
1st ionization energy: 546.7 kJ/mole
2nd ionization energy: 1085 kJ/mole
3rd ionization energy: 2405 kJ/mole
Electronegativity: 1.12
Electron affinity: 50 kJ/mole
Specific heat: 0.18 J/gK
Heat atomization: 178 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,25,8,2
Electron Shell Configuration: [Xe] 4f7 6s2
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: bcc: body-centered cubic
Color: silvery-white
Hardness: mohs
Toxicity: ?
Characteristics: hard
Uses: alloys, color TV phosphor


Reactions


Reaction with air: vigorous, =>Eu2O3
Reaction with 6M HCl: mild, =>H2, EuCl3
Reaction with 15M HNO3: mild, =>Eu(NO3)3
Reaction with 6M NaOH: ?


Other Forms


Number of isotopes: 2
Oxide(s): Eu2O3
Hydride(s): EuH2
Chloride(s): EuCl2 EuCl3


Radius


Atomic Radius: 208 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): 131 pm
Ionic radius (3+ ion): 108.7 pm


Conductivity


Thermal conductivity: 13.9 J/m-sec-deg
Electrical conductivity: 11 1/mohm-cm
Polarizability: 27.7 A^3


Abundance


Source: Monazite(phosphate),bastnaesite
Relative abundance solar system: -1.012 log
Abundance earth's crust: 0.1 log
Estimated crustal abundance: 2.0 milligrams per kilogram
Estimated oceanic abundance: 1.3×10-7 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Europe) In 1890 Boisbaudran obtained basic fractions from samarium-gadolinium concentrates which had spark spectral lines not accounted for by samarium or gadolinium. These lines subsequently have been shown to belong to europium. The discovery of europium is generally credited to Demarcay, who separated the rare earth in reasonably pure form in 1901. The pure metal was not isolated until recent years.


Sources


Europium has been identified spectroscopically in the sun and certain stars. Seventeen isotopes are now recognized. Europium isotopes are good neutron absorbers and are being studied for use in nuclear control applications.


Properties


As with other rare-earth metals, except for lanthanum, europium ignites in air at about 150 to 1800C. Europium is about as hard as lead and is quite ductile. It is the most reactive of the rare-earth metals, quickly oxidizing in air. It resembles calcium in its reaction with water. Bastnasite and monazite are the principal ores containing europium.


Uses


Europium oxide is now widely used as a phospor activator and europium-activated yttrium vanadate is in commercial use as the red phosphor in color TV tubes. Europium-doped plastic has been used as a laser material. With the development of ion-exchange techniques and special processes, the cost of the metal has been greatly reduced in recent years.

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