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Antimony


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Atomic symbol: Sb
Atomic number: 51
Atomic weight: 121.75
Atomic volume: 18.23 cm3/mol
Density: 6.684 g/cm3
Period Number: 5
Group number: 15
Group name: Metal, Nitrogen group
Element classification: Semi-metal


States


Phase at room temperature: Solid
Melting Point: 903.94 K
Boiling point: 1860 K
Heat of fusion: 19.870 kJ/mol
Heat of vaporization: 77.140 kJ/mol


Energies


Ionization Energy: 8.64 eV
1st ionization energy: 833.7 kJ/mole
2nd ionization energy: 1594.9 kJ/mole
3rd ionization energy: 2441.1 kJ/mole
Electronegativity: 2.05
Electron affinity: 103 kJ/mole
Specific heat: 0.21 J/gK
Heat atomization: 262 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,18,18,5
Electron Shell Configuration: [Kr] 4d10 5s2 5p3
Minimum oxidation number: -3
Maximum oxidation number: 5
Minimum common oxidation number: 0
Maximum common oxidation no: 5


Appearance & Characteristics


Structure:: rhombohedral
Color: bluish-white
Hardness: 3.15 mohs
Toxicity: ?
Characteristics: brittle; 5 forms
Uses: Pb alloy(battery), dyeing


Reactions


Reaction with air: mild, w/ht, =>Sb2Ox x=3-5
Reaction with 6M HCl: none
Reaction with 15M HNO3: mild, =>Sb2O5
Reaction with 6M NaOH: none


Other Forms


Number of isotopes: 2
Oxide(s): Sb2O3 Sb2O4 Sb2O5
Hydride(s): SbH3
Chloride(s): SbCl3 SbCl5


Radius


Atomic Radius: 140 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 90 pm


Conductivity


Thermal conductivity: 24.4 J/m-sec-deg
Electrical conductivity: 25.641 1/mohm-cm
Polarizability: 6.6 A^3


Abundance


Source: Stibnite (sulfide)
Relative abundance solar system: -0.510 log
Abundance earth's crust: -0.7 log
Estimated crustal abundance: 2×10-1 milligrams per kilogram
Estimated oceanic abundance: 2.4×10-4 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(Gr. anti plus monos - "a metal not found alone") Antimony was recognized in compounds by the ancients and was known as a metal at the beginning of the 17th century and possibly much earlier.


Sources


Antimony is not abundant, but is found in over 100 mineral species. It is sometimes found natively, but more frequently it is found as the sulfide stibnite.


Properties


Antimony is a poor conductor of heat and electricity. Antimony and many of its compounds are toxic.


Uses


Antimony is finding use in semiconductor technology for making infrared detectors, diodes and Hall-effect devices. It greatly increases the hardness and mechanical strength of lead. Batteries, antifriction alloys, type metal, small arms and tracer bullets, cable sheathing, and minor products use about half the metal produced. Compounds taking up the other half are oxides, sulfides, sodium antimonate, and antimony trichloride. These are used in manufacturing flame-proofing compounds, paints ceramic enamels, glass, and pottery.

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