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Aluminium


Aluminium Alloy Sections in Russia  Aluminium alloy sections in Russia
Aluminium Scrap and the Scrap-Based Products Market Research in Russia  Aluminium scrap in Russia
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Ferrochrome market research in the CIS  Ferrochrome market in CIS
Atomic symbol: Al
Atomic number: 13
Atomic weight: 26.98154
Atomic volume: 10.0 cm3/mol
Density: 2.702 g/cm3
Period Number: 3
Group number: 13
Group name: Metal
Element classification: Metal


States


Phase at room temperature: Solid
Melting Point: 933.57 K
Boiling point: 2740 K
Heat of fusion: 10.790 kJ/mol
Heat of vaporization: 293.40 kJ/mol


Energies


Ionization Energy: 5.986 eV
1st ionization energy: 577.6 kJ/mole
2nd ionization energy: 1816.6 kJ/mole
3rd ionization energy: 2744.7 kJ/mole
Electronegativity: 1.61
Electron affinity: 42.6 kJ/mole
Specific heat: 0.90 J/gK
Heat atomization: 326 kJ/mole atoms


Oxidation & Electrons


Shells: 2,8,3
Electron Shell Configuration: [Ne] 3s2 3p1
Minimum oxidation number: 0
Maximum oxidation number: 3
Minimum common oxidation number: 0
Maximum common oxidation no: 3


Appearance & Characteristics


Structure:: fcc: face-centered cubic
Color: silvery
Hardness: 2.8 mohs
Toxicity: ?
Characteristics: passivated: surface oxide
Uses: Al cans & foil,reflectors


Reactions


Reaction with air: mild, w/ht =>Al2O3
Reaction with 6M HCl: mild, =>H2, AlCl3
Reaction with 15M HNO3: passivated
Reaction with 6M NaOH: mild, =>H2, [Al(OH)4]-


Other Forms


Number of isotopes: 1
Oxide(s): Al2O3
Hydride(s): AlH3
Chloride(s): AlCl3Al2Cl6


Radius


Atomic Radius: 143 pm
Ionic radius (1- ion): pm
Ionic radius (1+ ion): pm
Ionic radius (2- ion): pm
Ionic radius (2+ ion): pm
Ionic radius (3+ ion): 67.5 pm


Conductivity


Thermal conductivity: 237 J/m-sec-deg
Electrical conductivity: 376.676 1/mohm-cm
Polarizability: 8.3 A^3


Abundance


Source: Bauxite (oxide)
Relative abundance solar system: 4.929 log
Abundance earth's crust: 4.9 log
Estimated crustal abundance: 8.23×104 milligrams per kilogram
Estimated oceanic abundance: 2×10-3 milligrams per liter
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 
 


History


(L. alumen: alum) The ancient Greeks and Romans used alum as an astringent and as a mordant in dyeing. In 1761 de Morveau proposed the name alumine for the base in alum, and Lavoisier, in 1787, thought this to be the oxide of a still undiscovered metal.

Wohler is generally credited with having isolated the metal in 1827, although an impure form was prepared by Oersted two years earlier. In 1807, Davy proposed the name aluminum for the metal, undiscovered at that time, and later agreed to change it to aluminum. Shortly thereafter, the name aluminum was adopted to conform with the "ium" ending of most elements, and this spelling is now in use elsewhere in the world.

Aluminium was also the accepted spelling in the U.S. until 1925, at which time the American Chemical Society officially decided to use the name aluminum thereafter in their publications.


Sources


The method of obtaining aluminum metal by the electrolysis of alumina dissolved in cryolite was discovered in 1886 by Hall in the U.S. and at about the same time by Heroult in France. Cryolite, a natural ore found in Greenland, is no longer widely used in commercial production, but has been replaced by an artificial mixture of sodium, aluminum, and calcium fluorides.

Aluminum can now be produced from clay, but the process is not economically feasible at present. Aluminum is the most abundant metal to be found in the earth's crust (8.1%), but is never found free in nature. In addition to the minerals mentioned above, it is also found in granite and in many other common minerals.


Properties


Pure aluminum, a silvery-white metal, possesses many desirable characteristics. It is light, it is nonmagnetic and nonsparking, stands second among metals in the scale of malleability, and sixth in ductility.


Compounds


The compounds of greatest importance are aluminum oxide, the sulfate, and the soluble sulfate with potassium (alum). The oxide, alumina, occurs naturally as ruby (Al2O3), sapphire, corundum, and emery, and is used in glassmaking and refractories. Synthetic ruby and sapphire are used in lasers for producing coherent light.


Uses


It is extensively used for kitchen utensils, outside building decoration, and in thousands of industrial applications where a strong, light, easily constructed material is needed.

Although its electrical conductivity is only about 60% that of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties.

These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. These coatings soon form a thin layer of the protective oxide and do not deteriorate as do silver coatings. They are used to coat telescope mirrors and to make decorative paper, packages, and toys.

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